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Chemistry of molecular solids

Code: 72806
ECTS: 5.0
Lecturers in charge: izv. prof. dr. sc. Dominik Cinčić - Lectures
Lecturers: Vinko Nemec - Seminar
Take exam: Studomat
Load:

1. komponenta

Lecture typeTotal
Lectures 30
Seminar 15
* Load is given in academic hour (1 academic hour = 45 minutes)
Description:
CONTENT:
Molecular crystals: crystal symmetry, close packing, Kitaigorodsky coefficient, structure and conformation of molecules. Molecular interactions in solid state: Van der Waals forces, polar interactions, hydrogen bonds, halogen bonds. Topology of molecular interactions and topologic descriptors. Crystallisation: oversaturation and metastable state, nucleation, crystal growth, methods of crystallisation. Polymorphism: thermodynamic and kinetic control, polymorph nucleation, phase rule, metastable form, physical and chemical properties of polymorphs. Isomorphous, amorphous and isostructural compounds. Multicomponent systems: solvates, salts, cocrystals, physical and chemical properties, application. Solid state reactions: mechanochemical synthesis (neat and liquid-asisted grinding), microwave-assisted synthesis, photochemical synthesis and single-crystal-to-single-crystal reactions.

LEARNING OUTCOMES:
1. To compare and to contrast the difference between ionic, covalent and molecular crystals.
2. To classify molecular interactions in the solid state.
3. To explain the topology of molecular interactions and topologic descriptors.
4. To define the terms: hydrate, solvate, salt, cocrystal.
5. To classify and to explain methods for crystallization of molecular crystals from solution.
6. To explain the terms polymorphism and isomorphism.
7. To classify and to explain methods of the mechanochemical synthesis in the solid state.
8. To compare and to contrast the difference between covalent and supramolecular mechanosynthesis.
9. To describe the terms: reaction without solvents, aging reaction, grinding reaction.
10. To give a short oral lecture on given subject.
Literature:
  1. 1. D. Braga i F. Grepioni, Making Crystals by Design: Methods, Techniques and Applications, Wiley-VCH, Weinheim, 2007.
    2. G. S. Rohrer, Structure and Bonding in Crystalline Materials, Cambridge Univ. Press, Cambridge, 2006.
    3. G. R. Desiraju, Crystal Engineering: The Design of Organic Solids, Elsevier, Amsterdam, 1989.
1. semester
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Analytical and inorganic chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Analytical and organic chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Analytical and physical chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Analytical chemistry and biochemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Biochemistry and organic chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Biochemistry and physical chemistry
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Inorganic and organic chemistry
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Inorganic and physical chemistry
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Inorganic chemistry and biochemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Physical and organic chemistry

3. semester
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Analytical and inorganic chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Analytical and organic chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Analytical and physical chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Analytical chemistry and biochemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Biochemistry and organic chemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Biochemistry and physical chemistry
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Inorganic and organic chemistry
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Inorganic and physical chemistry
Izborni predmeti anorganska i strukturna kemija - Mandatory smjer - Inorganic chemistry and biochemistry
Izborni predmeti izvan odabranih grana - Mandatory smjer - Physical and organic chemistry
Consultations schedule: