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Supramolecular Chemistry

Code: 152810
ECTS: 5.0
Lecturers in charge: prof. dr. sc. Mladen Žinić - Lectures
dr. sc. Leo Frkanec - Lectures
prof. dr. sc. Vladislav Tomišić - Lectures
Take exam: Studomat
Load:

1. komponenta

Lecture typeTotal
Lectures 13
Seminar 2
* Load is given in academic hour (1 academic hour = 45 minutes)
Description:
Definition and development of supramolecular chemistry. Examples of natural supramolecular systems. Characteristics of biochemical processes - organic chemistry in vivo. Classification of Host-Guest complexes, synthesis and properties of crown ethers and cryptands. Binding constants, extraction and transport of metal cations through natural and artificial membranes. Natural and synthetic ionophores. Concept of synthetic receptor and molecular recognition. Calixarenes, carcerands, spherands and polytopic receptors. Molecular recognition of amino acids, peptides and nucleotides. Chemosensors. Thermodynamics of supramolecular complexes. Nature of supramolecular interactions, non-covalent bonding interactions in supramolecular chemistry: electrostatic, hydrogen bond, van der Waals and aromatic. Solvophobic effects. Supramolecular synthesis and supramolecular chirality. Biological mimics and supramolecular catalysis. Development of functional supramolecular systems. Self-assembly and self-organization, supramolecular polymers, gels and fibers. Design new supramolecular functional materials nano-dimensional assemblies, molecular nanotechnology, molecular switches and artificial machines. Training: Design and Molecular modelling (Sybyl-X).
Literature:
  1. OBVEZNA LITERATURA:
    J. W. Steed, J. L. Atwood, Supramolecular Chemistry, 2nd Edition, John Wiley & Sons, Chichester 2009.
    J.-M. Lehn: Supramolecular Chemistry. Concepts and Perspectives, Verlag Chemie, Weinheim 1995.
    H. Dugas: Bioorganic Chemistry. A Chemical Approach to Enzyme Action, 2nd. Ed., Springer-Verlag, New York, 1988.
    H.-J. Schneider, H. Durr (ur.): Supramolecular Organic Chemistry and Photochemistry, Verlag Chemie, Weinheim 1991.
  2. DOPUNSKA LITERATURA:
    B. L. Feringa, Angew. Chem. Int. Ed. (56) 2017, 11080
    J.-P. Sauvage, ibid. (56) 2017, 11080
    J. F. Stoddart, ibid. (56) 2017, 11094.
    J.-M. Lehn, Angew. Chem. Int. Ed. Engl. 27 (1988) 89; 29 (1990) 1304.
    D. J. Cram, ibid. 27 (1988) 1009.
    J. Rebek, Jr., Chem. Brit. (1994) 286.
    J. Fraser Stoddart (ur.): D. J. Cram, J. M. Cram: Container Molecules and Their Guests, Monographs in Supramolecular Series, Royal Soc. Chem., Cambridge 1994.
    A. W. Czarnik: Fluorescent Chemosensors for Ion and Molecule Recognition, ACS Symp. Ser. 538, 1992.
    V. Balzani, F. Scandola: Supramolecular Photochemistry, Ellis Horwood Ser. in Physical Chem. 1991.
    C. J., Pedersen, ibid. 27 (1988) 1053.
1. semester
Izborni kolegiji za smjer analitička kemija - Mandatory smjer - Analytical chemistry
Izborni kolegiji za smjer biokemija - Mandatory smjer - Biochemistry
Izborni kolegiji za smjer anorganska i strukturna kemija - Mandatory smjer - Inorganic and structural chemistry
Izborni kolegiji za smjer organska kemija - Mandatory smjer - Organic chemistry
Izborni kolegiji za smjer fizikalna kemija - Mandatory smjer - Physical chemistry

3. semester
Izborni predmeti doktorski studij kemije - Mandatory smjer - Analytical chemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Biochemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Inorganic and structural chemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Organic chemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Physical chemistry
Consultations schedule: