Basic definitions and concepts of electroanalysis: ions, electrolytes, charge. Galvanic article and electrolysis. Electrochemical cells, thermodynamic properties and electrode potentials. Electric double layers. Basics of kinetics and mechanisms of electrochemical reactions (velocity, voltage dependence, transport processes - diffusion, migration and convection). Faraday and non-faraday processes. Diffusion and kinetics controlled processes. Reversibility, quasi reversibility, irreversibility of the reactions. Electrochemical experiment: different electrode types, "green electrochemistry", electrochemical cell, basic electrolytes, instrumentation (analogue - potentiostat, galvanostat and digital), electrochemical sensors, nanoparticle based sensors. Overview of electroanalytical methods with their backgrounds : trigger and response signals (Potentiometry, Voltammetry, Amperometry, Electrogravimetry, Kulometry, Spectroscopy, Electrochemical Impedance Spectroscopy). Examples of the use of electroanalytical methods in analytical chemistry related to professional and scientific-research work.
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- OBVEZNA LITERATURA:
I. Piljac, (Ur.), Elektroanalitičke metode. Teorijske osnove, mjerne naprave i primjena, Udžbenik Sveučilišta u Zagrebu, RMC d.o.o., Zagreb, 1995.
I. Piljac, (Ur), Senzori fizikalnih veličina i elektroanalitičke metode, Udžbenik Sveučilišta u Zagrebu MediaPrint, Zagreb, 2010.
A. J. Bard, I. Rubinstein (Ur.), Electroanalytical Chemistry, A Series of Advances, Vol. 20, Marcel Delkker, Inc., New York, 1998 A.J. Bard, L.R. Faulkner (Ur.), Electrochemical methods: Fundamentals and Applications", John Wiley and Sons, New York, 2000.
F.Scholz, (Ur.), Electroanalytical methods, Springer-Verlag, Berlin, 2002.
J. Wang (Ur.), Analytical Electrochemistry, 3rd Edition, John Wiley and Sons, New York, 2006.
F. Scholz, F. (Ur.), Electroanalytical Methods: Guide to Experiments and Application, New York 2010.
- DOPUNSKA LITERATURA:
Suvremeni opsežniji revijski članci i znanstvene monografije
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