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Inorganic chemistry laboratory 2

Code: 41056
ECTS: 4.0
Lecturers in charge: prof. dr. sc. Višnja Vrdoljak - Lectures
Lecturers: Mladen Borovina - Laboratory exercises
Marijana Đaković - Laboratory exercises
Dino Kuzman - Laboratory exercises
Ana Palčić - Laboratory exercises
Biserka Prugovečki - Laboratory exercises
Marina Tašner - Laboratory exercises
Take exam: Studomat
Load:

1. komponenta

Lecture typeTotal
Laboratory exercises 60
* Load is given in academic hour (1 academic hour = 45 minutes)
Description:
1. Diketonate complexes of transition metals
a) Synthesis of tris(2,4-pentanedionato)iron(III)
b) Synthesis of tris(2,4-pentanedionato)cobalt (III)
c) Synthesis of oxobis(2,4-pentanedionato)vanadium(IV)
d) Synthesis of tris(2,4-pentanedionato)manganese(III)
e) Synthesis of tris(2,4-pentanedionato)chromium(III),
f) Synthesis of bis(2,4-pentanedionato)manganese(II)
2. Metal oxalates
a) Synthesis of potassium tris(oxalato)chromate(III) trihydrate,
Determination of the complex composition
b) Synthesis of potassium tris(oxalato)ferate(III) trihydrate
Determination of the complex composition
c) Synthesis of potassium tris(oxalato)manganate(III) trihydrate
Determination of the complex composition
3. Metal complexes of N-donor ligands
a) Synthesis of hexaamminecobalt(III) nitrate
determination of the complex composition
b) Synthesis of hexaamminenickel(II) chloride
Determination of the complex composition
c) Synthesis of ammonium diamminetetranitrocobaltate(III), (Erdmann's salt)
d) Synthesis of bis(2,3-butanedione dioximato)chloropyridinecobalt(III)

4. Thiocianato complexes
a) Synthesis of tetramethylammonium dioxotetrakis(thiocianato-N)molybdate(VI)
Synthesis of HCNS
b) Synthesis of potassium tetrakis(thiocianato-N)cobaltate(II),
c) Synthesis of trans-dipyridinebis(thiocianato-N)copper(II),
d) Synthesis of potassium hexakis(thiocianato-N)chromate(III) tetrahydrate,

5. Synthesis of Cr(II), Cr(V), Mo(V) i Cu(I) complexes by reduction
a) Synthesis of potassium tetraperoxochromate(V),
Determination of the complex composition
b) Synthesis of oxo-dioxotetrakis(2,4-pentanedionato)dimolybdenum(V)
Synthesis of bis(2,4-pentanedionato)dioxomolybdenum(VI)
Determination of the compex composition
c) Synthesis of tetrakis(acetato)diquadichromium(II)
d) Synthesis of tris(thiourea)copper(I) sulfate monohydrate

6. Isomerism in coordination chemistry
a) Synthesis of pentaamminebromocobalt(III) chloride and pentaamminesulfatocobalt(III) bromide
b) Synthesis of pentaamminechlorocobalt(III) chloride
c) Synthesis of pentaamminenitro-N-cobalt(III) chloride, and pentaamminenitrito-O-cobalt(III) chloride
d) Synthesis of tris(ethilenediamine)chromium(III) chloride trihydrate
During the semester student have to make seven laboratory experiments (including identification of some products by chemical or instrumental methods of analysis- X-ray structure analysis on powder and monocrystal sample).

LEARNING OUTCOMES
The experiments are chosen to supplement and enhance the lecture content of the associated Inorganic chemistry 2 course.
After completion of this course, the successful student will be able to:
1. Apply laboratory skills to synthesize and separate complex compounds associated with Inorganic chemistry 2 course using published reactions, protocols, standard laboratory equipment,
2. Demonstrate safe laboratory skills (including proper handling of materials and chemical waste) for particular laboratory experiments.
3. Analyse and interpret data of the carried out experimental protocol
4. Characterize prepared complex compounds using modern instrumentation.
5. Identify a given inorganic compound based on a series of chemical reactions.
6. Demonstrate knowledge of the element classification to predict important properties of chemical compounds, including stability, solubility, redox properties and reactivity.
Literature:
  1. M. Cindrić, Z. Popović, V. Vrdoljak, Priprava anorganskih spojeva I i II (interna skripta)
  2. W. L. Jolly, The Synthesis and Characterization of Inorganic Compounds, Waveland Press., 1991.
  3. G. S. Girolami, T. B. Rauchfuss, R. J. Angelici, Synthesis and Technique in Inorganic Chemistry, 3. izd., University Science Books, Sausalito, 1999.
Prerequisit for:
Enrollment :
Enrolled : Inorganic chemistry 2
6. semester
Mandatory course - Mandatory studij - Chemistry
Consultations schedule: