Department of...
 
Statistical...
 
Statistical Thermodynamics and Irreversible...
 
Code: 152847
ECTS: 8.0
Lecturers in charge: prof. dr. sc. Vladislav Tomišić - Lectures
doc. dr. sc. Josip Požar - Lectures
doc. dr. sc. Gordan Horvat - Lectures
Take exam: Studomat
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1. komponenta

Lecture typeTotal
Lectures 20
Seminar 5
* Load is given in academic hour (1 academic hour = 45 minutes)
Description:
Theoretical Phenomenological Thermodynamics: Mathematical and physical background (Pfaff forms , homogeneous functions, Jacobians, characteristic functions). Axiomatics (principle of Carathéodory). Relativistic generalisation. Theoretical Statistical Thermodynamics: Theory of probability. Principles of quantum mechanics. Stationary model (the method of ensembles). Classical approximation, the partition function method. The evaluation of the stationary model, density matrix. Fluctuations. The method of molecular partition function. Models based on canonical ensemble: Debye model of crystal, real gases, electrolyte solutions (P. Debye i E. Hückel, J. E. Mayer, Monte Carlo methods and molecular dynamics). Irreversible processes: Generalised fluxes and forces, linear phenomenological relations (Onsager). Nonlinear phenomena (dissipative structures, oscillating chemical reactions). Thermochemistry: Thermometry. Calorimetry. Standard thermodynamic properties. Tables of thermodynamic properties.
Literature:
  1. OBVEZNA LITERATURA:
    E. A. Guggenheim: Thermodynamics, 5. izd. North-Holland, Amsterdam 1967.
    H. Margenau, G. M. Murphy: The Mathematics of Physics and Chemistry, Vol. I, Van Nostrand, New York 1956. (pogl. 1, 11, 12), Vol. II, Van Nostrand, New York 1964. (pogl. 8).
    M. L. McGlashan: Chemical Thermodynamics, Academic Press, London 1979.
    G. Nicolis, I. Prigogine: Self_organization in Non_equilibrium Systems, Wiley, New York 1977; (ruski prijevod: Samoorganizacija v neravnovesnyh sistemah, Mir, Moskva 1979).
    Vl. Simeon: Termodinamika, Školska knjiga, Zagreb 1980.
    J. R. Waldram: The Theory of Thermodynamics, Cambridge University Press, Cambridge 1985.
    J. O. M. Bockris, A. K. N. Reddy: Modern Electrochemistry, 2. izd., Vol. 1, Plenum Press, New York 1998.
  2. DOPUNSKA LITERATURA:
    revijalni članci i znanstvene monografije
1. semester
Izborni kolegiji za smjer analitička kemija - Mandatory smjer - Analytical chemistry
Izborni kolegiji za smjer biokemija - Mandatory smjer - Biochemistry
Izborni kolegiji za smjer anorganska i strukturna kemija - Mandatory smjer - Inorganic and structural chemistry
Izborni kolegiji za smjer organska kemija - Mandatory smjer - Organic chemistry
Temeljni kolegiji iz fizikalne kemije - Mandatory smjer - Physical chemistry

3. semester
Izborni predmeti doktorski studij kemije - Mandatory smjer - Analytical chemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Biochemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Inorganic and structural chemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Organic chemistry
Izborni predmeti doktorski studij kemije - Mandatory smjer - Physical chemistry
Consultations schedule:
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