Equilibria in the solid/liquid systems and supersaturation: solubility product, concentrations and activities in supersaturated solutions, some critical values. Kinetics and mechanisms: foramtion of solid phase from supersaturated solutions (nucleation and crystal growth); dissolution. Properties of the solid phase: crystal shapes and their size distribution, hydrodinamic factors, chemical properties, taložni dijagrami, utjecaj primjesa. Secundary changes of the solid phase: transformation, coagulation, agglomeration. Application.
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- OBVEZNA LITERATURA:
A. E. Nielsen: Kinetics of Precipitation, Pergamon Press, Oxford 1964.
A. G. Walton: The Formation and Properties of Precipitates, Interscience, New York 1967.
O. Soehnel, J. Garside: Precipitation, Butterworth-Heinemann, Oxford 1992.
H. Fueredi-Milhofer, A. G. Walton: Principles of Precipitation of Fine Particles, u: G. D. Parfitt (ur.): Dispersion of Powders in Liquids, 3. izd., Applied Science Publ., London 1981, str. 203-272.
A. E. Nielsen: Precipitates: Formation, Coprecipitation and Aging, u: I. M. Kolthoff, P. J. Elving (ur.): Treatise on Analytical Chemistry, 2. izd., Vol. 3, Wiley, New York 1983, str. 269-347.
B. Težak, Disc. Faraday Soc. 1966, 175; Croat. Chem. Acta 40 (1968) 63; 42 (1970) 81.
A. E. Nielsen, Croat. Chem. Acta 42 (1970) 319; Pure Appl. Chem. 53 (1981) 2025.
A. E. Nielsen, M. Toft: J. Crystal Growth 67 (1984) 278, 289.
Lj. Brečević, D. Kralj: Kinetics and Mechanisms of Crystal Growth in Aqueous Systems, u: N. Kallay (ur.): Interfacial Dynamics, Marcel Dekker, New York 1999.
H. Colfen and M. Antonietti, Angew. Chem. Int. Ed. 2005, 44, 5576 - 5591.
H. Colfen and S. Mann, Angew. Chem. Int. Ed. 2003, 42, 2350 - 2365.
D. Gebauer, M. Kellermeier, J.D. Gale, L. Bergstrom and H. Colfen: Chem. Soc. Rev., 2014, 43, 2348-2371.
- DOPUNSKA LITERATURA:
revijalni članci i znanstvene monografije
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