1. komponenta

Lecture type	Total
Laboratory exercises	60

Reaction calorimetry: enthalpy of reaction in the Daniell cell. Dissociation equilibrium: determination of equilibrium constant of deprotonation of methyl rot using spectrophotometry method. Distribution: determination of equilibrium constant of distribution of ammonia between water and chloroform. Solubility of gases: determination of equilibrium constant of oxygen dissolution in water. Colligative properties: determination of ebulioscopic and cryoscopic constants. Adsorption: adsorption equilibrium, the Langmuir and Freundlich isotherms. Chemical kinetics: temperature dependence of reaction rates, determination of reaction rate constant of ethyl acetate hydrolysis at different temperatures, calculation of activation energy. Kinetics of ionic reactions 1: primary salt effect, second order kinetics. Kinetics of ionic reactions 2: primary salt effect, pseudo-first order kinetics. Conductometric titration: determination of concentration of NaOH solution using conductometric titration, verification of results by means of automatic potentiometric titration.

LEARNING OUTCOMES:

After completing the laboratory course student should be able to:
- independently measure basic physico-chemical properties (pH, conductivity, absorbance, temperature, electromotive force, etc ...) using modern instrumentation and classical techniques
- collect and interpret the experimental results
- apply standard mathematical methods for solving the chemical problems and analysing the experimental results.
- apply various physico-chemical models for interpretation of experimental results
- analyse the experimental results regarding the reproducibility of measurements, sensitivity of measurements and predictable errors.
- analyse the factors that influence the obtained results.

1. 1. N. Kallay, S. Žalac, T. Preočanin, D. Kovačević, S. Žalac, G. Horvat, J. Požar: Praktikum fizikalne kemije 2, skripta, Zavod za fizikalnu kemiju, Kemijski odsjek, PMF, Zagreb, 2009.
2. P. W. Atkins, J. de Paula: Atkins' Physical Chemistry, 10. izdanje, Oxford Univ. Press, Oxford, 2014.
3. R. J. Silbey, R. A. Alberty: Physical Chemistry, 4. izdanje, Wiley, New York, 2004.
4. T. Cvitaš, I. Planinić, N. Kallay, Rješavanje računskih zadataka u kemiji II dio, Hrvatsko kemijsko društvo, Zagreb, 2014.
5. T. Cvitaš, N. Kallay: Fizičke veličine i jedinice Međunarodnog sustava, Školska knjiga, Zagreb, 1980.
6. T. Cvitaš, Fizikalna kemija, rukopis u pripremi.

Enrollment :
Passed : Physical chemistry laboratory 1

Mandatory course - Regular study - Chemistry