PROJEKT / PROJECT: MOLART
IP-06-2016-4221
Trajanje / Duration: 1.3. 2017 - 28. 2. 2021.
Financiranje / Funding: HRVATSKA ZAKLADA ZA ZNANOST / CROATIAN SCIENCE FPUNDATION
VODITELJ PROJEKTA / PRINCIPAL INVESTIGATOR: prof. dr. sc. Višnja Vrdoljak
INSTITUCIJE KOJE SUDJELUJU U PROJEKTU / INSTITUTIONS
- Prirodoslovno-matematički fakultet, Sveučilište u Zagrebu / Faculty of Science, University of Zagreb
- Medicinski Fakultet, Sveučilište u Zagrebu / School of Medicine, University of Zagreb
- Tekstilno-tehnološki fakultet, Sveučilište u Zagrebu / Faculty of Textile Technology, University of Zagreb
- INA-industrija nafte d.d.
- Dectris Ltd., Baden
NAZIV PROJEKTA / PROJECT TITLE
Metalosupramolekulske strukture i anorgansko-organski polioksometalatni hibridi
Metallosupramolecular architectures and inorganic-organic polyoxometalate based hybrides
SAŽETAK
Glavna ideja projekta temelji se na principima koordinacijske kemije u dizajnu i sintezi novih MoVI metalosupramolekulskih struktura i organsko-anorganskih hibridnih polioksometalatnih materijala. Sinteza novih spojeva bazirat će se na “bottom-up” pristupu, odnosno njihovoj pripravi iz građevnih blokova nastalih in situ kako u otopini tako i u čvrstom stanju. To će omogućiti ispitivanje procesa samoudruživanja i kristalnog rasta navedenih sustava. Poveznica svih segmenata istraživanja je i u pronalaženju uvjeta neophodnih u kontroli sastava, strukture i svojstava ciljnih spojeva. Očekuje se da će ovo istraživanje dati uvid u mehanizme ispitivanih reakcija i omogućiti tumačenje utjecaja različitih inter- i intramolekulskih interakcija na svojstva višedimenzionalnih sustava ili njihovih građevnih blokova. Metode koje će se koristiti u sintezi organskih, metalosupramolekulskih i anorgansko-organskih polioksometalatnih hibrida bit će modificirane metode otopinske kemije, ali će se koristiti i metodologije zelene kemije. Istraživanja termički induciranih reakcija u čvrstom stanju predstavljaju dodatni izazov ovoga projekta.
Predloženi projekt uključivat će organsku, koordinacijsku, analitičku teorijsku, te biokemiju i medicinsku kemiju. Sastoji se od sljedećih dijelova: (i) dizajna i sinteze multifunkcionalnih hidrazonskih N,O-donorskih liganada i ispitivanja njihovih svojstava; (ii) sinteze novih MoVI metalosupramolekulskih sustava; (iii) sinteze novih hibridnih organsko-anorganskih polioksometalatnih spojeva; (iv) karakterizacije svih priređenih spojeva; (v) kvantno-kemijskih proračuna i teorijskih tumačenja eksperimentalnih rezultata s ciljem boljeg razumijevanja i poboljšanja ispitivanih procesa; (vi) ispitivanja kemijskih i fizikalnih svojstava priređenih spojeva; (vii) ispitivanja bioloških svojstava odabranih spojeva.
ABSTRACT
The main idea of the project is to apply principles of coordination chemistry to design and synthesise new MoVI metallosupramolecular architectures and POM-based organic-inorganic hybrid materials. Such systems will be developed via a bottom-up approach combining suitable building blocks generated in situ in solution as well as in the solid state. The complexity in their construction is an invaluable opportunity to study the self-assembly and crystal growth processes. Links between all segments of this research are in finding suitable conditions that are necessary to control the composition and/or structural features of target architectures. It is expected that our investigation will give insight into particular reaction mechanisms and provide explanation for the influence of different inter- and intramolecular interactions on properties of high-dimensional compounds or their building blocks. Methods used in the synthesis of organic, metallosupramolecular and inorganic-organic hybrids will be modified and performed in accordance to conventional, but also green, chemical methodologies. Investigations of thermally induced reactions in the solid state are additional challenging part of the project.
The proposed project will combine organic, coordination, analytical, theoretical, biochemical and medicinal chemistry. The proposed project consists of the following parts: (i) design and synthesis of multifunctional hydrazone N,O-donor ligands and study of their properties; (ii) synthesis of novel MoVI metallosupramolecular architectures; (iii) preparation of novel hybrid organic-inorganic compounds based on polyoxomolybdates; (iv) characterisation of all prepared compounds; (v) quantum chemical calculations and theoretical support to the experimental research which will be used to understand and guide the improved efficiency of the studied processes; (vi) investigation of chemical and physical properties of prepared compounds; (vii) investigation of biological properties of selected compounds.
PROJEKTNI TIM / PROJECT TEAM
Prirodoslovno-matematički fakultet / Faculty of Science: prof. dr. sc. Marina Cindrić, prof. dr. sc. Tomica Hrenar, Dino Kuzman, mag. chem. (od 1.3.2019.), Mirna Mandarić, mag. chem., dr. sc. Jana Pisk, izv. prof. dr. sc. Ines Primožič, prof. dr. sc. Biserka Prugovečki, izv. prof. dr. sc. Mirta Rubčić, doc. dr. sc. Vladimir Stilinović (do 15. 12. 2018.), Edi Topić, mag. chem. (od 15.12.2018.), prof. dr. sc. Višnja Vrdoljak
Medicinski Fakultet, School of Medicine: dr. sc. Danijela Cvijanović, doc. dr. sc. Vladimir Damjanović, prof. dr. sc. Jasna Lovrić,
Tekstilno-tehnološki fakultet / Faculty of Textile Technology: prof. dr. sc. Gordana Pavlović (do 1. 3. 2019.)
INA-industrija nafte d.d.: dr. sc. Jelena Parlov Vuković
Dectris Ltd: dr. sc. Dubravka Šišak Jung
PUBLIKACIJE / PUBLICATIONS
I RAZDOBLJE / 1ST PROJECT PERIOD
- J. Pisk, T. Hrenar, M. Rubčić, G. Pavlović, V. Damjanović, J. Lovrić, M. Cindrić, V. Vrdoljak, Comparative studies on conventional and solvent free synthesis toward hydrazones: application of PXRD and chemometric data analysis in mechanochemical reaction monitoring, CrystEngComm, 20 (2018) 1804-1817. DOI: 10.1039/C7CE02136D
- M. Cindrić, V. Stilinović, M. Rubčić, G. Medak, D. Šišak Jung, V. Vrdoljak, Supramolecular assembly of oxalatomolybdates controlled by the hydrogen bonding potential of Co(III)-ammine cations, CrystEngComm, 20 (2018) 1889-1898. DOI: 10.1039/C7CE02205K
II RAZDOBLJE / 2ND PROJECT PERIOD
- V. Vrdoljak, B. Prugovečki, I. Primožič, T. Hrenar, D. Cvijanović, J. Parlov Vuković, R. Odžak, M. Skočibušić, S. Prugovečki, J. Lovrić, D. Matković-Čalogović and M. Cindrić, An integrated approach (synthetic, structural and biological) to the study of aroylhydrazone salts, New J. Chem., 42 (2018) 11697-11707. DOI: 10.1039/C8NJ01457D
- M. Rubčić, J. Pisk, K. Pičuljan, V. Damjanović, J. Lovrić, V. Vrdoljak, Symmetrical disubstituted carbohydrazides: from solid-state structures to cytotoxic and antibacterial activity, J. Mol. Struct., 1178 (2019) 222-228. DOI: 10.1016/j.molstruc.2018.09.092
- D. Cvijanović, J. Pisk, G. Pavlović, D. Šišak-Jung, D. Matković-Čalogović, M. Cindrić, D. Agustin, V. Vrdoljak, Discrete mononuclear and dinuclear compounds containing a MoO22+ core and 4-aminobenzhydrazone ligands: synthesis, structure and organic-solvent-free epoxidation activity, New J. Chem., 43 (2019) 1791-1802. DOI: 10.1039/C8NJ04074E
- M. Cindrić, T. Hrenar, V. Damjanović, V. Stilinović, D. Kuzman, J. Pisk, I. Primožić, V. Vrdoljak, Mechanochemical synthesis of (poly)oxalatomolybdates: In situ reaction monitoring by PXRD, Inorg. Chim. Acta., 488 (2019) 80-85. DOI: 10.1016/j.ica.2019.01.006
III RAZDOBLJE / 3rd PROJECT PERIOD
- J. Pisk, M. Rubčić, D. Kuzman, M. Cindrić, D. Agustin, V. Vrdoljak, Molybdenum(VI) complexes of hemilabile aroylhydrazone ligands as efficient catalysts for greener cyclooctene epoxidation: an experimental and theoretical approach, New J. Chem., 43 (2019) 5531-5542. DOI: 10.1039/C9NJ00229D
- V. Vrdoljak, M. Mandarić, T. Hrenar, I. Đilović, J. Pisk, G. Pavlović, M. Cindrić, D. Agustin, Geometrically constrained molybdenum(VI) metallosupramolecular architectures: conventional Synthesis versus vapor and thermally induced solid-state structural transformations, Cryst. Growth. Des., 19 (2019) 3000-3011. DOI: 10.1021/acs.cgd.9b00231.
- V. Damjanović, J. Pisk, D. Kuzman, D. Agustin, V. Vrdoljak, V. Stilinović, M. Cindrić, The synthesis, structure and catalytic properties of the [Mo7O24(μ-Mo8O26)Mo7O24]16− anion formed via two intermediate heptamolybdates [Co(en)3]2[NaMo7O24]Cl·nH2O and (H3O)[Co(en)3]2[Mo7O24]Cl·9H2O, Dalton Trans., 48 (2019) 9974-9983. DOI: 10.1039/C9DT01625B
- V. Damjanović, D. Kuzman, V. Vrdoljak, S. Muratović, D. Žilić, V. Stilinović, M. Cindrić, Hydrothermal Reactions of [CoIII(C2O4)(NH3)4]+ and Polyoxomolybdates: Depolymerization of Polyoxomolybdates and in Situ Reduction of Cobalt, Cryst. Growth Des., 19 (2019) 6763–6773. DOI: 10.1021/acs.cgd.9b01142.
- M. Mandarić, B. Prugovečki, D. Cvijanović, J. Parlov Vuković, J. Lovrić, M. Skočibušić, R. Odžak, M. Cindrić, V. Vrdoljak, Vapour- and solvent-mediated crystalline transformations in Mo(VI) hydrazone complexes controlled by noncovalent interactions, CrystEngComm, 21 (2019) 6281–6292. DOI: 10.1039/C9CE01273G
IV RAZDOBLJE / 4TH PROJECT PERIOD
- D. Kuzman, V. Damjanović, V. Vrdoljak, V. Stilinović, M. Cindrić, Directing role of the synthetic route on the self-assembly process of MoO42- units to Mo7O242- or Mo22O7416- ions, Inorg. Chim. Acta., 510 (2020) 119765. DOI:10.1016/j.ica.2020.119765
- J. Pisk, D. Agustin, V. Vrdoljak, Tetranuclear molybdenum(VI) hydrazonato epoxidation (pre)catalysts: Is water always the best choice?, Catal Commun, 142 (2020) 106027. DOI: 10.1016/j.catcom.2020.106027
- E. Topić, J. Pisk, D. Agustin, M. Jenderlin, D. Cvijanović, V. Vrdoljak, M. Rubčić, Discrete and polymeric ensembles based on dinuclear molybdenum(VI) building blocks with adaptive carbohydrazide ligands: from the design to catalytic epoxidation, New J. Chem., 44(19) (2020) 8085-8097. DOI: 10.1039/d0nj01045f
- E. Topić, I. Landripet, M. Duguin, J. Pisk, I. Đilović, V. Vrdoljak, M. Rubčić, Coordinating and supramolecular prospects of unsymmetrically substituted carbohydrazides, New J. Chem., 44(31) (2020) 13357-13367. DOI: 10.1039/D0NJ03106B
- J. Pisk, I. Đilović, T. Hrenar, D. Cvijanović, G. Pavlović, V. Vrdoljak, Effective methods for the synthesis of hydrazones, quinazolines, and Schiff bases: reaction monitoring using a chemometric approach, RSC ADV., (10) (2020) 38566. DOI:10.1039/D0RA06845D
- J. Mihalinec, M. Pajski, P. Guillo, M. Mandarić, N. Bebić, J. Pisk, V. Vrdoljak, Alcohol Oxidation Assisted by Molybdenum Hydrazonato Catalysts Employing Hydroperoxide Oxidants, Catalyst, (11(8)) (2021) 881. DOI: 10.3390/catal11080881
- A. Bafti, M. Razum, E. Topić, D. Agustin, J. Pisk, V. Vrdoljak, Implication of oxidant activation on olefin epoxidation catalysed by Molybdenum catalysts with aroylhydrazonato ligands: Experimental and theoretical studies, Mol. Catal., (512) (2021) 111764. DOI: 10.1016/j.mcat.2021.111764
- N. Bebić, E. Topić, M. Mandarić, T. Hrenar, V. Vrdoljak, Extending the structural landscape of Mo(VI) hydrazonato inorganic-organic POM-hybrids: an experimental and computational study, CrystEngComm, (2021) DOI: 10.1039/D1CE00861G
- D. Kuzman, V. Damjanović, V. Stilinović, M. Cindrić, V. Vrdoljak, The role of mono- and dicarboxylic acids in the building of oxomolybdates containing {MoO4}, {Mo2O5}, {Mo2O6}, {Mo3O8}, {Mo5O17}, {Mo5O18}, {Mo8O26}, and {SiMo12O40} units, New. J. Chem., (2021) DOI: 10.1039/D1NJ03280A
POZVANO PREDAVANJE / INVITED LECTURES
- M. Cindrić, V. stilinović, V. Vrdoljak, Supramolekulski sustavi funkcionaliziranih polioksomolibdata – od sinteze do svojstava, II simpozij suprmolekulske kemije, 12. 12. 2018., Zagreb, Hrvatska.
https://supramolchem2018.irb.hr/Simpozij - V. Vrdoljak, Metallosupramolecular Assemblies: the Synergy Between NMR Spectroscopy and Crystallography, Adriatic NMR Conference, 6-9.06.2019., Mali Ston, Hrvatska.
- M. Rubčić, Carbohydrazides and dihydrazones: The aspects of their solid-state and solution chemistry, Adriatic NMR Conference 2020, 22.-24.09.2020., Peroj, Hrvatska.
KONFERENCIJE / CONFERENCES
I RAZDOBLJE / 1ST PROJECT PERIOD
- M. Cindrić, V. Stilinović, M. Rubčić, V. Vrdoljak, Supramolecular complexes based on molybdates and different Co(III)-ammine units via electrostatic and H-bonding interactions, 4th EuCheMS Inorganic Chemistry conference, 2.-5. 7. 2017., Copenhagen, Danska.
- M. Rubčić, J. Pisk, M. Cindrić, V. Vrdoljak, Symmetrical and asymmetrical carohydrazides: A solid-state and solution study, Adriatic NMR, 16.-18. 6. 2017., Mali Ston, Hrvatska.
- J. Pisk, M. Rubčić, D. Cvijanović, V. Damjanović, J. Lovrić, M. Cindrić, V. Vrdoljak, Biological testings of mechanochemicaly obtained aroyl hydrazones as perspective ligands for metal complexes, 14th International symposium on applied bioinorganic chemistry-ISABC14, 7.-10. 6. 2017, Toulouse, Francuska.
II RAZDOBLJE / 2ND PROJECT PERIOD
- D. Cvijanović, J. Pisk, G. Pavlović, D. Šišak-Jung, M. Cindrić, V. Vrdoljak, Dinuclear Mo(VI) complexes with 4-aminobenoylhydrazone derivatives: a slid-state amd solution study, Adriatic NMR, 15.-17. 6. 2018., Mali Ston, Hrvatska.
- V. Vrdoljak, M. Mandarić, D. Kuzman, M. Rubčić, G. Pavlović, J. Pisk, M. Cindrić, Metallosupramolecular architectures derived from aroylhydrazone ligands, European Chemistry Conference 2018, ECC-2018, 4.-6. 7. 2018, Rome, Italy.
- D. Cvijanović, J. Pisk, G. Pavlović, D. Šišak-Jung, M. Cindrić, D. Agustin, and V. Vrdoljak, The mononuclear MoO22+complexes with stereochemically rigid 4-aminobenzhydrazide based ligands, 31st European Crystallographic Meeting, ECM31, 22.-27. 8. 2018, Oviedo, Spain.
- A. Eberhardt, V. Stilinović, V. Vrdoljak, M. Cindrić, Sinteza i karakterizacija kompleksnih soli, [CoC2O4(NH3)4]2[Co(C2O4)2(H2O), [(C2O4)2Co(μ-OH)2Co(NH3)4]·3H2O, 3Na[CoC2O4(NH3)4][Mo2O4(µ-O)2(C2O4)2] i [CoC2O4(NH3)4]4[Mo3O6(μ-O)2(C2O4)3(H2O)2]·nH2O,
5. Simpozij studenata kemičara, 27.10. 2018., Zagreb, Hrvatska. - V. Damjanović, J. Pisk, V. Vrdoljak, V. Stilinović, M. Cindrić, Synthetic route influence on the formation of supramolecular Co(III)-Mo(VI) double-complex salts, IUPAC Postgraduate Summer School on Green Chemistry, 7.-13. 7. 2018., Venice, Italy
III RAZDOBLJE / 3RD PROJECT PERIOD
- D. Kuzman,V. Vrdoljak, V. Stilinović, M. Cindrić, Molekulska i kristalna struktura polioksomolibdata građenih od [Mo7O24]6- i [CoMo6(OH)6O18]6- aniona, 26. hrvatski skup kemičara i kemijskih inženjera, 9.-12. 4. 2019, Šibenik, Hrvatska.
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E. Topić, M.Rubčić, J. Pisk, V. Vrdoljak, Structural insights into complexes and polyoxomolybdate salts derived from asymmetric carbohydrazones, 6. hrvatski skup kemičara i kemijskih inženjera, 9.-12. 4. 2019, Šibenik, Hrvatska.
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D. Cvijanović, M. Mandarić, B. Prugovečki, J. Lovrić, Jasna, M. Cindrić, V. Vrdoljak,
Synthesis, characterization and cytotoxicity of dioxomolybdenum(VI) complexes with 4- methoxysalicylaldehyde isonicotinoyl hydrazone, 6. hrvatski skup kemičara i kemijskih inženjera, 9.-12. 4. 2019, Šibenik, Hrvatska.
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M. Mandarić, V. Vrdoljak, T. Hrenar, I. Đilović, M. Cindrić, Vapor and thermally induced solid-state structural transformations, 17th International Conference on Chemistry and the Environment, 16-20.06.2019., Thessaloniki, Grčka.
- M. Cindrić, V. Stilinović, V. Damjanović, D. Kuzman, S. Muratović, D. Žilić, V. Vrdoljak, From [Mo7O24]2- to Anderson-type anion [CoII(OH)6Mo6O18]4− in presence of [Co(ox)(NH3)4](NO3) and under hydrothermal conditions, 2nd Euro Chemistry Conference, 17-19.06.2019., Valencia, Španjolska.
- M. Mandarić, V. Vrdoljak, Vapor and thermally induced solid-state structural transformations, Solid-State Science & Research Meeting, 27-29.06.2019., Zagreb, Hrvatska.
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E. Topić, V. Stilinović, On the molar volume of multicomponent crystals, Solid-State Science & Research Meeting, 27-29.06.2019., Zagreb, Hrvatska.
- M. Rubčić, E. Topić, J. Pisk, V. Vrdoljak, Hybrid polyoxomolybdate systems based on rationally designed asymmetric carbohydrazones, 32nd European Crystallographic Meeting, 18-23.08.2019., Beč, Austrija.
- J. Pisk, D. Cvijanović, D. Kuzman, M. Rubčić, D. Agustin, V. Vrdoljak, Greener cyclooctene epoxidation with molybdenum complexes derived from aminobenzohydrazone ligands, Advanced Energy Materials Conference, 11-13.09.2019., Guildford, Engleska.
- E. Topić, M. Rubčić, J. Pisk, I. Đilović, V. Vrdoljak, Structural and supramolecular diversity of asymmetric carbohydrazones, Chemistry Conference for Young Scientists, 19.-21.02.2020., Blankenberge, Belgija.
- M. Mandarić, D. Cvijanović, B. Prugovečki, I. Kekez, V. Vrdoljak, Comprehensive study on molybdenum(VI) complexes of 3-methoxysalicylaldehyde isonicotionylhydrazone, Chemistry Conference for Young Scientists, 19.-21.02.2020., Blankenberge, Belgija.
- D. Kuzman, V. Damjanović, V. Vrdoljak, V. Stilinović, M. Cindrić, Synthesis and characterization of [Co(en)3]2[Mo7O24]·8H2O, Chemistry Conference for Young Scientists, 19.-21.02.2020., Blankenberge, Belgija.
- D. Cvijanović, J. Pisk, I. Đilović, J. Lovrić, V. Vrdoljak, Synthesis, characterization, cytotoxicity and antimicrobial activity of salicylaldehyde based aroylhydrazones, Chemistry Conference for Young Scientists, 19.-21.02.2020., Blankenberge, Belgija.
IV RAZDOBLJE / 4TH PROJECT PERIOD
- E. Topić, K. Pičuljan, V. Vrdoljak, M. Rubčić, Solid-state and solution behaviour of aryl dihydrazones, Adriatic NMR Conference 2020, 22.-24.09.2020., Peroj, Hrvatska.
- D. Kuzman, V. Damjanović, V. Stilinović, M. Cindrić, V. Vrdoljak, The influence of reaction conditions on obtaining polyoxalatomolybdates of various nuclearity, 5. Simpozij studenata doktorskih studija PMF-a 2021, 24-25.04.2021., Zagreb, Hrvatska.
- M. Mandarić, N. Bebić, E. Topić, V. Vrdoljak, Polyoxomolybdates of various nuclearities functionalized with Mo(VI) hydrazone complexes, 5. Simpozij studenata doktorskih studija PMF-a 2021, 24-25.04.2021., Zagreb, Hrvatska.
- E. Topić, M. Rubčić, V. Vrdoljak, Coordination polymers of the {MoO2 2+}-dihydrazone type as structurally and topologically versatile systems, Solid-State Science & Research, 10.-11.06.2021., Zagreb, Hrvatska.
- J. Pisk, Tetranuclear molybdenum(vi) hydrazonato epoxidation (pre)catalysts: Is water always the best choice?, 7th Edition of International Conference on Catalysis, Chemical Engineering and Technology, 17.-18.05.2021. (online)
LJETNE ŠKOLE / SUMMER SCHOOLS
- V. Damjanović, S, IUPAC Postgraduate Summer School on Green Chemistry, 7.-13. 7. 2018., Venice, Italy.
- M. Mandarić, 17th BCA/CCG Intensive Teaching School in X-Ray Structure Analysis, 6.-14.04. 2019., Durham, Ujedinjeno Kraljevstvo
- D. Kuzman, 4th International Summer School of Crystallography, 2.-8.06. 2019., Hamburg, Njemačka
- E. Topić, The Zürich School of Crystallography 2019: Bring Your Own Crystals, 16.-27.06. 2019., Zürich, Švicarska
DIPLOMSKI RADOVI/ DIPLOMA THESIS
- Kuzman, Dino
Mononuklearni i dinuklearni kompleksi molibdena(vi) s derivatima 2-benzhidrazida, 2017., diplomski rad, Prirodoslovno-matematički fakultet, Zagreb, (mentor: V. Vrdoljak) - Mandarić, Mirna
Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima,
2018, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb (mentor: V. Vrdoljak) - Zrnc, Katrina
Strukturne transformacije mononuklearnih kompleksa molibdena(VI) s derivatima 4-aminobenzhidrazida, 2018, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb (mentor: V. Vrdoljak) - Medak, Glorija
Reakcije nastajanja oksalatomolibdata s Co(III) etilendiaminskim kationima, 2018, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb (mentor: M. Cindrić) - Šuntić, Iris Renata
Simetrični i asimetrični karbonohidrazidi izvedeni iz 2,3-dihidroksibenzaldehida i 2,4-dihidroksibenzaldehida, 2019, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb (mentor: M. Rubčić) - Mihalinec, Josipa
Synthesis and application of molybdenum based catalyst for oxidation reactions, 2019, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb, (mentor: J. Pisk; P. Guillo) - Razum, Marta
Synthesis and catalytic activity of novel molybdenum hydrazonato complexes, 2019, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb, (mentor: J. Pisk; D. Agustin) - Bafti, Arijeta
Priprava i katalitička primjena kompleksnih spojeva molibdena(VI) s derivatima 2, 4- dihidroksibenzaldehida, 2019, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb, (mentor: J. Pisk) - Eberhardt, Antonio
Sinteza i karakterizacija polioksomolibdatnih soli Co(III), 2020, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb (mentor: M. Cindrić) - Bebić, Nikol
Koordinacijski polimeri i polioksometalatni hibridi molibdena(VI), 2020, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb, (mentor: V. Vrdoljak) - Pajić, Mario
Utjecaj kompleksa kobalta(III) na nastajanje polioksometalatnih vrsta, 2020, diplomski rad, Prirodoslovno-matematički fakultet, Zagreb, (mentor: M. Cindrić)
REKTOROVA NAGRADA/RECTOR'S AWARD
- N. Bebić, Sinteza, karakterizacija i strukturne transformacije kompleksnih spojeva Mo(VI) s derivatima 2,4- dihidroksibenzaldehida, 2020.